Hi,
Your wife will need to review the guidance on residence at
RDR3 and take the residency tests, to determine her tax residency status in the 2023 to 2024 tax year.
This will determine whether she needs to declare the overseas earnings in 2023 to 2024 on a self assessment tax return.
If your wife is UK tax resident for 2024 to 2025, then she will be taxable in the UK on her Overseas employment income.
As this income is taxable in the USA, she will need to claim a foreign tax credit in her self assessment tax return, so that she does not pay the tax twice:
Check how to register for Self Assessment
Thank you.