Hi Andrew,
If you have 2 employments, and your now secondary employment was previously your primary, this could affect the allocation of your allowances.
You can use the following link to check your tax code/s is/are correct.
How-to-update-your-tax-code.
If you are unable to resolve your query this way, please contact HMRC to check your tax codes.
Income Tax: general enquiries
Thank you.