Hi,
You can see guidance on Income Tax rates here:
Income Tax rates and Personal Allowances
When claiming higher rate tax relief in your Self Assessment tax return, you increase the 20% threshold of £50270, by the gross amount of pension payments you made in the tax year. By increasing the 20% rate, you are in effect reducing the highest rates of tax you pay by the same amount. This means you pay more tax at 20% and less at the other rates, thus giving tax relief.
If you claimed tax relief on EIS/SEIS shares, the Self Assessment tax calculation reduces your tax liability by a straight forward credit of the amount of investment at 30%, for example, your tax liability is £20000 and you invest £33333 in EIS shares, £33333 at 30% is £10000. Your tax liability of £20000 is reduced by £10000, if you have paid more than £10000 tax, the difference is refunded to you.
Thank you.