Hi,
The payments on account requested are advance payments for the tax year 2024 to 2025. The first is requested on the 31st January 2025, 10 months into the 2024 to 2025 tax year, while the second is requested 4 months after the end of this tax year. You can read more about payments on account, and the reasons for their scheduling, here:
Understand your Self Assessment tax bill
Thank you.