Hi,
Please have a look at Article 15, Dependent Personal Services, of the UK / Canada double taxation agreement. In general, it advises that a UK resident, who has employment income in Canada, is taxable only in the UK on this income, unless, the individual is in Canada, undertaking the work. Paragraph 2(a) states the circumstances, that would allow the income to be taxed in Canada:
1978 Canada/UK Double Taxation Convention (2014 consolidated version
If your employment income is not taxable in Canada, you will need to request a Certificate of Residence from HMRC, which you would need to send to the Canadian Revenue Service, to request no tax is deducted from your employment income, which you will declare on a Self Assessmen tax return. You can see guidance here:
How to apply for a certificate of residence to claim tax relief abroad
If tax is deductable in Canada, you would need to claim Foreign Tax Credit Relief in your Self Assessment tax return for up to 100% of the tax deducted, so that you do not have to pay the tax twice.
Thank you.