Hi Ian,
The address to write to is:
Pay As You Earn and Self Assessment, HM Revenue and Customs, BX9 1AS.
For assistance regarding setting up an online account, you will need to contact our online helpdesk:
Technical support with HMRC online services
If you are unable to set up an online account, then once the POA details are submitted you can contact HMRC for assistance:
Income Tax: general enquiries
Thank you