Hi,
The tax payable against self employment income, whether arising in the UK or overseas, cannot be collected automatically and tax codes deductions that can be made are those that are expressly permitted by statute. EIM31600 provides details of deductions that are permitted by legislation.
EIM31611 - Deductions from general earnings: where to find instructions
Self assessment has two payments on account, that allow the payment of tax in advance, arising from the net profits from self employment.
Thank you.