Hi Arkturus,
Before you cash the second payble order, you should contact HMRC, to ensure this is not a mistake.
If you complete a self assessment tax return, you can webchat at
Self Assessment: general enquiries (out telephone lines are closed until 4 September).
If you do not complete tax returns, you can phone the Pay as you earn helpline at 0300 200 3300, text relay 18001 0300 200 3300 or from overseas +44 13 5535 9022 (Monday to Friday: 8am to 6pm Closed on Saturdays, Sundays and Bank Holidays).
Thank you.