Hi
As long as you are selling your 'old stuff' and not trading as a business, to make a profit, then there is nothing you need to do.
If you are trading as a business and your turnover exceeds £1000.00, you will need to register for self assessment, as self employed, using your goverment gateway user ID and password.
Your existing government gateway user ID and password allows you to access HMRC onlne services (
HMRC online services: sign in or set up an account)
or things like your personal or business tax account, Self Assessment, Corporation Tax, PAYE for employers and VAT.
Thank you