Hi 5454Can,
The tax treaty between the UK and Canada allows for you to claim full relief on your monthly pension payments in the UK, including State Pension.
(lump sums are a different matter and are taxable in the UK).
You will need to download the UK/Canada (Form Canada/Individual) here:
Double Taxation: UK/Canada (Form Canada/Individual).
Using the notes complete the form to declare all of your UK pensions and State pension if appropriate, sign and date the form and send it to the Canadian Revenue Service.
They will validate the form and return it to you.
You then send this to HMRC at the address at the top of the form.
Each time you receive a new pension from the UK, you need to fill this form in and follow the process above.
Thank you.