Hi,
For the specific movement types, requires users to identify in DE 2/3 the need for any commercial or official documents, such as invoices, packing lists, licences, certificates or authorisations to be declared on the customs declaration or Customs Clearance Request (CCR).
Codes which begin with a letter are referred to as Union Codes. These take precedence over any National document codes, they include licences, preference certificates and authorisations.
Codes begin with a number and are referred to as National Document Codes, they are used to declare any national documentary requirements such as home office licences or HMRC forms
Please see below links for more guidance.
CDSSG04710 - Navigating the Tariff, Step 7 - Understanding document codes in CDS
CDSSG04700 - Navigating the Tariff, Step 7 - Document Codes: Contents
Thank you.